161 Introduction to Logarithmic Properties

LEARNING OBJECTIVES

By the end of this lesson, you will be able to:

  • Use the product rule for logarithms.
  • Use the quotient rule for logarithms.
  • Use the power rule for logarithms.
  • Expand logarithmic expressions.
  • Condense logarithmic expressions.
  • Use the change-of-base formula for logarithms.
Testing of the pH of hydrochloric acid.
Figure 1. The pH of hydrochloric acid is tested with litmus paper. (credit: David Berardan)

In chemistry, pH is used as a measure of the acidity or alkalinity of a substance. The pH scale runs from 0 to 14. Substances with a pH less than 7 are considered acidic, and substances with a pH greater than 7 are said to be alkaline. Our bodies, for instance, must maintain a pH close to 7.35 in order for enzymes to work properly. To get a feel for what is acidic and what is alkaline, consider the following pH levels of some common substances:

  • Battery acid: 0.8
  • Stomach acid: 2.7
  • Orange juice: 3.3
  • Pure water: 7 (at 25° C)
  • Human blood: 7.35
  • Fresh coconut: 7.8
  • Sodium hydroxide (lye): 14

To determine whether a solution is acidic or alkaline, we find its pH, which is a measure of the number of active positive hydrogen ions in the solution. The pH is defined by the following formula, where a is the concentration of hydrogen ion in the solution

[latex]\begin{cases}\text{pH}=-\mathrm{log}\left(\left[{H}^{+}\right]\right)\hfill \\ \text{ }=\mathrm{log}\left(\frac{1}{\left[{H}^{+}\right]}\right)\hfill \end{cases}\\[/latex]

The equivalence of [latex]-\mathrm{log}\left(\left[{H}^{+}\right]\right)\\[/latex] and [latex]\mathrm{log}\left(\frac{1}{\left[{H}^{+}\right]}\right)\\[/latex] is one of the logarithm properties we will examine in this section.

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